MATHESON TRI-GAS, INC. -- BUTYL BENZENE -- -
===================== Product Identification ===================== Product ID:BUTYL BENZENE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:BUTYL BENZENE CAS:104-51-8 Fraction by Wt: 100% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: irritation, vomiting, headache, symptoms of drunkenness, coma LONG TERM EXPOSURE: lung damage SKIN CONTACT: SHORT TERM EXPOSURE: irritation, headache, symptoms of drunkenness LONG TERM EXPOSURE: same as effects reported in short term exposure EYE CONTACT: SHORT TERM EXPOSURE: irritation, tearing LONG TERM EXPOSURE: same as effects reported in short term exposure INGESTION: SHORT TERM EXPOSURE: vomiting, headache, symptoms of drunkenness, coma LONG TERM EXPOSURE: lung damage Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: DO NOT induce vomiting. Never make an unconscious person vomit or drink fluids. If vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention. NOTE TO PHYSICIAN: For inhalation, consider oxygen. For ingestion, consider gastric lavage, catharsis and activated charcoal slurry. ===================== Fire Fighting Measures ===================== Flash Point:160 F (71 C) (OC) Autoignition Temp:770 F (410 C) Lower Limits:0.8% Upper Limits:5.8% Extinguishing Media:regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material ocombustion by-products. Stay upwind and keep out of low areas. Unusual Fire/Explosion Hazard:Severe fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. ================== Accidental Release Measures ================== Spill Release Procedures:Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. Ventilation:Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health BUTYL BENZENE: No occupational exposure limits established. ================== Physical/Chemical Properties ================== Boiling Pt:356 F (180 C) Melt/Freeze Pt:-116 F (-82 C) Vapor Pres:1 mmHg @ 23 C Vapor Density:4.6 Spec Gravity:0.9 pH:Not available Evaporation Rate & Reference:Not available Solubility in Water:insoluble Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless ODOR:odorless Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. Hazardous Decomposition Products:Thermal decomposition products: miscellaneous decomposition products Thermal decomposition products: miscellaneous decomposition products Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:BUTYL BENZENE: LOCAL EFFECTS: Irritant: inhalation, skin, eye ACUTE TOXICITY LEVEL: Insufficient Data. TARGET ORGANS: central nervous system ===================== Ecological Information ===================== Ecological:ECOTOXICITY DATA: INVERTEBRATE TOXICITY: 340 ug/L 48 hour(s) EC50 (Immobilization) Water flea (Daphnia magna) ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Butyl benzenes ID NUMBER: UN2709 HAZARD CLASS OR DIVISION: 3 PACKING GROUP: III LABELING REQUIREMENTS: Flammable liquid ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.